烟台市成品及散装食用油中塑化剂含量的调查
目的 了解烟台市售成品及散装食用油中塑化剂的迁移情况。方法 样品前处理依据GB/T 21911-2008, 乙酸乙酯: 环己烷(1:1, V:V)提取, 凝胶渗透色谱装置净化, 三重串联四级杆气质联用仪进行定性及定量分析。结果 成品油中塑化剂有少量检出, 而散装油的检出率很高, 主要为邻苯二甲酸二(2-乙基)己酯(DEHP)70%、邻苯二甲酸二丁酯(DBP)60%、邻苯二甲酸二异丁酯(DIBP)45%和邻苯二甲酸二异壬酯(DINP)20%, 超标率为DEHP 35.7%, DBP 58.3%。结论 市民在购买食用油时应尽量购买成品油, 购买散装的食用油时尽量不要使用非食品级的塑料桶盛放。
Objective To investigate the migration of plasticizers from plastic packaging into finished and bulk oil in Yantai. Methods According to GB/T 21911-2008, the samples were extracted with ethyl acetate: cyclohexane (1:1, V:V), and purified with gel permeation chromatography. Gas chromatography-tandem mass spectrometry (GC-MS/MS) was used for qualitative and quantitative analysis. Results There were low detection rates of plasticizers in finished oils, but high rates in bulk oils. The detection rates of bis(2-ethylhexyl) phthalate (DEHP), dibutyl phthalate (DBP), diisobutyl phthalate (DIBP) and diisononyl phthalate (DINP) were 70%, 60%, 45% and 20%, respectively, and the exceeding rates of DEHP and DBP were respectively 35.7% and 58.3%. Conclusion The finished oil should be chosen when shopping, and bulk oil should not be stored in the non-food-grade plastic bucket as far as possible.
标题：烟台市成品及散装食用油中塑化剂含量的调查
英文标题：Determination of plasticizers in finished and bulk oil in Yantai
作者：
王颖 烟台市疾病预防控制中心
刘海韵 烟台市疾病预防控制中心
张桂芳 烟台市疾病预防控制中心
王志昱 烟台市疾病预防控制中心
张晓瑜 烟台市疾病预防控制中心
孙兆鹏 烟台市疾病预防控制中心
中文关键词:塑化剂,气相色谱-串联质谱法,成品及散装食用油,塑料包装,
英文关键词:plasticizers,gas chromatography-tandem mass spectrometry,finished and bulk oil,plastic packaging,
发表日期：2016-08-29
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